SDS

A listing of SDS's
SAFETY DATA SHEET
Conductive Silver Liquid, SEM adhesive
1. IDENTIFICATION
Product Identifiers
Product Name:
Conductive Silver Liquid, SEM adhesive
Other Names:
N/A
Product Number(s):
I004, I0041
CAS Number:
-
Recommended use of the chemical and restriction on use
Fixative used in laboratory conditions.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia

(07) 4773 9444
www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia

(07) 4773 9444
www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
FLAMMABLE LIQUIDS - Category 2
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
REPRODUCTIVE TOXICITY (Fertility) - Category 1A
REPRODUCTIVE TOXICITY (Unborn child) - Category 1A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2
Label Elements
Signal Words
Danger
Hazard Statement(s)
H225: Highly flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s)
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or
competent authority to specify applicable ignition source(s).
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment
P241: Use explosion-proof electrical/ventilating/lighting/.../equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discarge.
P264: Wash with soap and water thoroughly after handling.
P280: Wear face protection. Specify type of equipment.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (OR HAIR): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do so. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/attention
P362: Take off contaminated clothing and wash before reuse.
P370+P378: In case of fire: Use dry chemical, CO₂, water spray (fog) or foam for extinction.
P403+P235: Store in a well-ventilated place. Keep cool.
P501: Dispose of contents and container in accordance with local, state and federal regulations.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
Inhalation of powder can cause mild, non-specific irritation of respiratory passages.
Ingestion:
Non-specific symptoms may occur due to presence of particulate material.
Eyes:
Particles are extremely irritating to eyes.
Skin:
In general, there is no effect of skin contact. Prolonged contact may produce skin discolouration.
Environment
Not available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Silver, metal
744-22-4
~56%
-
Protec Super Clear
-
Flammable Liquids Category 2 Eye Irritation Category 2A Skin Irritation Category 2 Specific Target Organ Toxicity - repeated exposure - Category 3 Chronic Aquatic Toxicity Category 2
Toluene
108-88-3-
~13.2-26.4%
See above in Protec Super Clear
Butanone
78-93-3
~4.4-13.2%
See above in Protec Super Clear
2-methoxy-1- methylethyl acetat
108-65-6
~0-4.4%
See above in Protec Super Clear
ethyl 3-ethoxypropionate
763-69-9
~0-4.4%
See above in Protec Super Clear
BBP
85-68-7
~0-4.4%
See above in Protec Super Clear
xylene
1330-20-7
~0-4.4%
See above in Protec Super Clear
bis(1,2,3,6,6- pentamethyl-4-piperidyl) sebacate Poly(oxy-1,2- ethanediyl),a-[3-[3-(2Hbenzotriazol-2
104810-48-2
~0-4.4%
See above in Protec Super Clear
Poly(oxy-1,2- ethanediyl),a-[3-[3-(2Hbenzotriazol-2-yl)-5- (1,1-dimethylethyl)-4- hydroxyphenyl]-1-
104810-47-1
~0-4.4%
See above in Protec Super Clear
Other ingredients, determined not to be hazardous according to Safe Work Australia criteria, and not
-
~0-4.4%
See above in Protec Super Clear
4. FIRST AID MEASURES
Ingestion
If patient is conscious, rinse particles from mouth with water; do not swallow. DO NOT induce vomiting. Never
give anything by mouth to an unconscious person. Obtain immediate medical attention.
Inhalation
Treat as dust inhalation. Remove patient to fresh air. Obtain medical treatment for prolonged respiratory irritation or difficulty in breathing.
Skin Contact
Wash affected area with soap and water to remove particles that may cling to skin. Remove contaminated clothing and shoes.
Eye Contact
Flush with water, including under lids, with gentle stream of water for fifteen minutes. Obtain immediate medical attention.
Other Information
Doctor to treat symptomatically.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
Use media appropriate for the surrounding fire. Recommended to use dry chemical, CO₂, water spray (fog) or
foam. DO NOT USE water jet.
HAZCHEM
Grinding finely divided powder, particularly with strong oxidisers, may result in explosion or fire when mixed with air in the proper proportions. Toxic metal fumes may be released in a fire situation. May cause carbon oxides when decomposing.
Special protective equipment and precautions for fire fighters
Wear self-contained breathing apparatus and full protective gear. Do not allow the material to enter waterways -toxic to the aquatic environment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material.
Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Environmental precautions
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Do not let the product enter drains/waterways.
Methods and materials for containment and clean up
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry intosewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
7. HANDLING AND STORAGE
Precautions for safe handling
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapour or mist. Avoid release to the environment. Refer to special instructions/safety data sheet. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.
Conditions for safe storage
Do not store above the following temperature: 50°C (122°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up.
Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials materials before handling or use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
Silver, metal
-
0.1
-
-
Toluene
50
191
150
574
Butanone
150
445
300
890
2-methoxy-1-methylethyl acetat
50
274
100
548
Ethyl 3-ethoxypropionate
100
610
-
-
BBP
-
5
-
Xylene
80
350
150
655
butan-1-ol
50 ppm
152 mg/m³
-
-
Engineering controls
Use only with adequate ventilation. Use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment/
Personal protective equipment
Eye and face protection
Chemical splash goggles or safety glasses with side shields
Skin protection
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
Respiratory protection
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Grey, lustrous liquid
Odour
Not available.
pH
Not determined.
Vapour Pressure
Negligible.{mmHg at °C}
Density
10.5 at 25°C
Boiling Point
81°C (177.8°F
Melting Point
960°C
Solubility
Insoluble in cold water.
Specific Gravity of Density
Not determined.
Flash Point
Closed cup: -6°C (21.2°F)
Flammable (Explosive) Limits
Not available.
Ignition Temperature
Not available.
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
Stable under normal conditions of use.
Possibility of hazardous reactions
Grinding finely divided powder, particularly with strong oxidisers, may result in explosion or fire when mixed with air in the proper proportions. Toxic metal fumes may be released in a fire situation.
Conditions to avoid
Contact with incompatible materials. Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid release to the
environment.
Incompatible materials
Strong acids, bases, and oxidising agents, ammonia, acetylene and hydrogen peroxide.
11. TOXICOLOGICAL INFORMATION
Acute effects
Contains material which causes damage to the following organs: brain.
Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, the reproductive system, liver, mucous membranes, heart, peripheral nervous system, gastrointestinal tract,
cardiovascular system, ears, eyes, lens or cornea, nose/sinuses.
Prolonged exposure to high concentrations can lead to argyria, a generalized grayish pigmentation of the skin and mucous membranes. Such symptoms usually occur after at least two years of exposure. There are no systemic effects, other symptoms, or physical disabilities known to be associated with this condition.
Inhalation of vapour/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Inhalation of high concentrations of vapour may affect the central nervous system.
Eye contact
Adverse symptoms may include the following:
pain
watering
redness
Skin contact
Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced foetal weight
increase in foetal deaths
skeletal malformations
Ingestion
Adverse symptoms may include the following:
stomach pains
reduced foetal weight
increase in foetal deaths
skeletal malformations
Inhalation
Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced foetal weight
increase in foetal deaths
skeletal malformations
Toxicity and irritation
Silver
TDLo: 330 mg/kg (rat, silver metal)
Toluene
LC 50Inhalation Vapour Rat 49 g/m³ 4 hours
LD50 Dermal Rabbit 8.39 g/kg -
LD50 Oral Rat 5580 mg/kg -
butanone
LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
butan-1-ol
LC50 Inhalation Vapour Rat 24000 mg/m³ 4 hours
LC50 Inhalation Vapour Rat 8000 ppm 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
LD50 Oral Rat 790 mg/kg -
2-methoxy-1-methylethyl acetate
LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 8532 mg/kg -
ethyl 3-ethoxypropionate
LD50 Dermal Rabbit 10 g/kg -
LD50 Oral Rat 3200 mg/kg -
benzyl butyl phthalate
LC50 Inhalation Vapour Rat >6700 mg/m³ 4 hours
LD50 Dermal Rabbit >10 g/kg -
LD50 Dermal Rat 6700 mg/kg -
LD50 Oral Rat 2.33 g/kg -
xylene
LD50 Dermal Rabbit >1.7 g/kg
Numerical measures of toxicity.
Route ATE value
Oral 7266.3 mg/kg
Dermal 79761.8 mg/kg
Inhalation (vapours) 735.3 mg
12. ECOLOGICAL INFORMATION
Ecotoxicity
Silver is toxic to aquatic life.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Water polluting material. May be harmful to the environment if released in large quantities.
Persistence and degradability
Ingredient name: Aquatic Half-Life Photolysis Biodegradability
Xylene Readily
Ingredient name: LogPow BCF Potential
Toluene 2.73 8.317637711
Butanone 0.29 - Low
Butan-1-ol 0.88 - Low
2-methoxy-1-methylethyl
acetate
0.56 - Low
BBP 4.73 16.218100973 Low
Xylene 3.16 7.4 to 18.5 Low
Bioaccumulative potential
Product/ingredient
name LogPow BCF Potential
toluene 2.73 8.32 low
butanone 0.29 - low
butan-1-ol 0.88 - low
2-methoxy-1-methylethyl
acetate
0.56 - low
benzyl butyl phthalate 4.73 16.22 low
xylene 3.16 7.4 to 18.5 low
Other adverse effects
No known side effects or critical hazards. Do not allow to enter drains or watercourses.
13. DISPOSAL CONSIDERATIONS
General information
The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
Grinding finely divided powder, particularly with strong oxidisers, may result in explosion or fire when mixed with air in the proper proportions. Toxic metal fumes may be released in a fire situation. May cause carbon oxides when decomposing.

UN Number
UN1263
Proper shipping name
Paint
Transport hazard class
3
Packing group
II
Environmental hazard
Yes
Special precautions for users
No information available.
Additional information
No information available.
15. REGULATORY INFORMATION
Poisons Schedule Number
Schedule 5
Other Information
No further relevant information available.
16. OTHER INFORMATION
SDS preparation date
1 November 2018
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.

... End of SDS ...