SAFETY DATA SHEET
Styrene Monomer, Polyester Resin
1. IDENTIFICATION
Product Identifiers
Product Name:
Styrene Monomer, Polyester Resin
Other Names:
Styrene Monomer, Polyester Resin Kit
Product Number(s):
14650, EMS14650
CAS Number:
100-42-5
Recommended use of the chemical and restriction on use
Laboratory chemicals.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS08 Health hazard
Carc. 1B H350 May cause cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 1 H372 causes damage to the hearing organs through prolonged or repeated exposure.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irritation 2A H319 Causes serious eye irritation.
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS08 Health hazard
Carc. 1B H350 May cause cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 1 H372 causes damage to the hearing organs through prolonged or repeated exposure.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irritation 2A H319 Causes serious eye irritation.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Hazard-determining components of labelling: STYRENE
Flammable liquid and vapour.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to the hearing organs through prolonged or repeated exposure.
Flammable liquid and vapour.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to the hearing organs through prolonged or repeated exposure.
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/ face protection.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/ face protection.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion:
Ge medical advice/attention if you feel unwell.
Eyes:
Rinse cautiously with wate for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention.
Skin:
(or hair) Remove/take off immediately all contaminated clothing. Rinse skin with wate/shower. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention.
Environment
In case of fire: Use CO₂, powder or water spray for extinction.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
No information available.
4. FIRST AID MEASURES
Ingestion
Call for a doctor immediately.
Inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, sand, extinguishing powder. Do not use water.
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents.
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Conditions for safe storage
Protect from heat and direct sunlight.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
100-42-5 STYRENE
50ppm
213mg/m³
100ppm
426mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Protective clothing.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Amber coloured viscous
Odour
Strong
pH
Not determined.
Vapour Pressure
6hPa
Density
1.1g/cm³
Boiling Point
145.2°C
Melting Point
-30.74°C
Solubility
0.24g/l
Specific Gravity of Density
Not available.
Flash Point
31°C
Flammable (Explosive) Limits
Lower: 1.2 Vol%
Upper: 8.9 Vol%
Upper: 8.9 Vol%
Ignition Temperature
480°C
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
100-42-5 STYRENE
Oral LD50 5000 mg/kg (rat)
Inhalative LC50/4 h 24mg/l (rat)
Oral LD50 5000 mg/kg (rat)
Inhalative LC50/4 h 24mg/l (rat)
Eye contact
Irritating effect.
Skin contact
Irritant to skin and mucous membranes.
Ingestion
Not available.
Inhalation
No sensitising effects known.
Toxicity and irritation
Not available.
12. ECOLOGICAL INFORMATION
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 2: hazardous for water.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
UN Number
UN2055
Proper shipping name
2055 STYRENE MONOMER, STABILIZED
Transport hazard class
Class 3 Flammable liquids.
Packing group
III
Environmental hazard
Not applicable.
Special precautions for users
Warning: Flammable liquids.
Hazard identification number (Kemler code): 39
EMS number: 3-07
Stowage Category: C
Stowage Code: SW1 Protected from sources of heat.
Hazard identification number (Kemler code): 39
EMS number: 3-07
Stowage Category: C
Stowage Code: SW1 Protected from sources of heat.
Additional information
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 1000mL
Transport category: 3
Tunnel restriction code: D/E
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 1000mL
Transport category: 3
Tunnel restriction code: D/E
15. REGULATORY INFORMATION
Poisons Schedule Number
S5
Other Information
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
SDS preparation date
11 May 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.