SAFETY DATA SHEET
Aniline-Alcohol Solution 1%
1. IDENTIFICATION
Product Identifiers
Product Name:
Aniline-Alcohol Solution 1%
Other Names:
Not available
Product Number(s):
26450-02, EMS26450-02
CAS Number:
Not available.
Recommended use of the chemical and restriction on use
Laboratory chemicals. Stains
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Water-react. 1 H260 In contact with water releases flammable gases which may ignite spontaneously.
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1A H350 May cause cancer.
STOT SE 2 H371 May cause damage to the central nervous system and the visual organs.
STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.
GHS07
Eye Irritation 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Water-react. 1 H260 In contact with water releases flammable gases which may ignite spontaneously.
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1A H350 May cause cancer.
STOT SE 2 H371 May cause damage to the central nervous system and the visual organs.
STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.
GHS07
Eye Irritation 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Hazard-determining components of labelling:
Ethyl alcohol
aniline
Methyl Alcohol
In contact with water releases flammable gases which may ignite spontaneously.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
May cause cancer.
May cause damage to the central nervous system and the visual organs.
Causes damage to organs through prolonged or repeated exposure.
Ethyl alcohol
aniline
Methyl Alcohol
In contact with water releases flammable gases which may ignite spontaneously.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
May cause cancer.
May cause damage to the central nervous system and the visual organs.
Causes damage to organs through prolonged or repeated exposure.
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from any possible contact with water, because of violent reaction and possible flash fire.
Handle and store contents under inert gas. Protect from moisture.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
Do not handle until all safety precautions have been read and understood.
Keep away from any possible contact with water, because of violent reaction and possible flash fire.
Handle and store contents under inert gas. Protect from moisture.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
Primary route(s) of entry
Not available
Human Health
Inhalation:
Not available
Ingestion:
Not available.
Eyes:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention.
Skin:
Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse.
Environment
In case of fire: Use CO₂, sand, extinguishing powder for extinction.
Store in a dry place. Store in a closed container.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Store in a dry place. Store in a closed container.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Ethyl alcohol
64-17-5
>50-≤100%
Not Available
Methyl Alcohol
67-56-1
>2.5-≤10%
Not Available
aniline
62-53-3
≤2.5%
Not Available
4. FIRST AID MEASURES
Ingestion
If symptoms persist consult doctor.
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
Use fire extinguishing methods suitable to surrounding conditions.
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewer/surface or ground water.
Dilute with plenty of water.
Do not allow to enter sewer/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents.
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Conditions for safe storage
Store in cool, dry conditions in well sealed receptacles.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
64-17-5 Ethyl alcohol
1000ppm
1880mg/m³
67-56-1 Methyl Alcohol
200ppm
262mg/m³
250ppm
328mg/m³
62-53-3 aniline
2ppm
7.6mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Wear protective clothing.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Clear liquid
Odour
Alcohol-like
pH
6.5-9
Vapour Pressure
Not determined
Density
Not determined
Boiling Point
100°C
Melting Point
Not determined
Solubility
Fully miscible
Specific Gravity of Density
Not determined
Flash Point
Not applicable
Flammable (Explosive) Limits
Not determined
Ignition Temperature
Spontaneously flammable in air
Formula
Not available
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
Contact with water releases flammable gases.
Conditions to avoid
No further relevant information.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
67-56-1 Methyl Alcohol
Oral LD50 5628 mg/kg (rat)
Dermal LD50 15800 mg/kg (rabbit)
62-53-3 aniline
Oral LD50 250 mg/kg (rat)
Dermal LD50 820 mg/kg (rabbit)
Inhalative LC50-4h 175 mg/l (mouse)
Oral LD50 5628 mg/kg (rat)
Dermal LD50 15800 mg/kg (rabbit)
62-53-3 aniline
Oral LD50 250 mg/kg (rat)
Dermal LD50 820 mg/kg (rabbit)
Inhalative LC50-4h 175 mg/l (mouse)
Eye contact
Irritating effect.
Skin contact
No irritant effect. Sensitisation possible through skin contact.
Ingestion
Not available
Inhalation
Not available
Toxicity and irritation
Harmful
Irritant
Irritant
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to fish.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 1: slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Harmful to aquatic organisms.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Harmful to aquatic organisms.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water
UN Number
UN2929
Proper shipping name
2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Transport hazard class
Class 6.1 Toxic substances
Label 6.1/3
Label 6.1/3
Packing group
II
Environmental hazard
Not applicable.
Special precautions for users
Warning: Toxic substances
Additional information
Not available.
15. REGULATORY INFORMATION
Poisons Schedule Number
67-56-1 Methyl Alcohol S5, S6
62-53-3 aniline S6
62-53-3 aniline S6
Other Information
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
SDS preparation date
15 March 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.