SAFETY DATA SHEET
N-Butyl Alcohol
1. IDENTIFICATION
Product Identifiers
Product Name:
N-Butyl Alcohol
Other Names:
N-Butyl Acetate
Product Number(s):
11920, 11921, EMS11920, EMS11921
CAS Number:
71-36-3
Recommended use of the chemical and restriction on use
Laboratory chemicals.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Flammable liquid and vapour.
Harmful if swallowed.
Causes skin irritation.
Causes serious eye damage.
May cause respiratory irritation. May cause drowsiness or dizziness.
Harmful if swallowed.
Causes skin irritation.
Causes serious eye damage.
May cause respiratory irritation. May cause drowsiness or dizziness.
Precautionary Statement(s)
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion:
Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Eyes:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Skin:
(or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention.
Environment
In case of fire: Use for extinction: CO, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Disposed of contents/container in accordance with local/regional/national/international regulations.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Disposed of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
No information available.
4. FIRST AID MEASURES
Ingestion
Call for a doctor immediately.
Inhalation
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, Powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7. HANDLING AND STORAGE
Precautions for safe handling
No special precautions are necessary if used correctly.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Wear protective clothing.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Colourless fluid
Odour
Alcohol-like
pH
7
Vapour Pressure
6.7hPa
Density
0.81g/cm³
Boiling Point
116-118°C
Melting Point
-89°C
Solubility
77g/l
Specific Gravity of Density
Not availability
Flash Point
35°C
Flammable (Explosive) Limits
Lower: 1.5 Vol%
Upper: 9.4 Vol%
Upper: 9.4 Vol%
Ignition Temperature
340°C
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
Oral LD50 790 mg/kg (rat)
Dermal LD50 3400 mg/kg (rabbit)
Inhalative LC50/4 h 8000 mg/l (rat)
Dermal LD50 3400 mg/kg (rabbit)
Inhalative LC50/4 h 8000 mg/l (rat)
Eye contact
Strong irritant with the danger of severe eye injury.
Skin contact
Irritant to skin and mucous membranes.
Ingestion
Not available.
Inhalation
No sensitising effects known.
Toxicity and irritation
Not available.
12. ECOLOGICAL INFORMATION
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 1: slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal musts be made according to official regulations.
Disposal musts be made according to official regulations.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
UN Number
UN1120
Proper shipping name
1120 BUTANOLS
Transport hazard class
Class 3 Flammable liquids.
Packing group
III
Environmental hazard
Not applicable.
Special precautions for users
Warning: Flammable liquids.
Hazard identification number (Kemler code): 30
EMS Number: 3-06
Stowage Category: A
Hazard identification number (Kemler code): 30
EMS Number: 3-06
Stowage Category: A
Additional information
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 1000mL
Transport category: 3
Tunnel restriction code: D/E
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 1000mL
Transport category: 3
Tunnel restriction code: D/E
15. REGULATORY INFORMATION
Poisons Schedule Number
S5, S6
Other Information
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
SDS preparation date
27 April 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.