SAFETY DATA SHEET
Colloidal Silver Liquid
1. IDENTIFICATION
Product Identifiers
Product Name:
Colloidal Silver
Other Names:
Colloidal Silver liquid
Product Number(s):
12630, 12630-SP, EMS12630
CAS Number:
Not available
Recommended use of the chemical and restriction on use
Laboratory chemicals
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Lam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS06 Skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed
GHS08 Health hazard
Carc. 1A H350 May cause cancer
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H336 May cause drowsiness or dizziness
Lam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS06 Skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed
GHS08 Health hazard
Carc. 1A H350 May cause cancer
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H336 May cause drowsiness or dizziness
Label Elements
Signal Words
Danger
Hazard Statement(s)
Highly flammable liquid and vapour.
Toxic if swallowed.
Causes skin irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Toxic if swallowed.
Causes skin irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flame/hot surfaces. No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fumes/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flame/hot surfaces. No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fumes/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Primary route(s) of entry
Not available
Human Health
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion:
If swallowed immediately call a POISON CENTER/doctor. Rinse mouth. Do NOT induce vomiting.
Eyes:
Not available
Skin:
(or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs get medical advice/attention.
Environment
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Toluene
108-88-3
>25-≤50%
Mixtures
Ethyl Alcohol
64-17-5
>2.5-≤10%
Mixtures
Ethyl Acetate
141-78-6
>2.5-≤10%
Mixtures
Propan-2-ol
67-63-0
>2.5-≤10%
Mixtures
1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
76-22-2
>2.5-≤10%
Mixtures
4. FIRST AID MEASURES
Ingestion
do not induce vomiting; call for medical help immediately.
Inhalation
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Other Information
Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore, medical observation for at least 48 hours after the accident. In case of irregular breathing or respiratory arrest provide artificial respiration.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Dilute with plenty of water. Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Keep ignition sources away - Do not smoke. Protect from heat. Protect against electrostatic charges.
Conditions for safe storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
Toluene
50ppm
191mg/m³
150ppm
574mg/m³
Ethyl alcohol
1000ppm
1880mg/m³
-
Ethyl acetate
200ppm
720mg/m³
400ppm
1440mg/m³
Propan-2-ol
400ppm
983mg/m³
500ppm
1230mg/m³
1,7,7-Trimethylbicyclo[2.2.1]heptane-2-one
2ppm
12mg/m³
3ppm
19mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Not available.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Grey liquid
Odour
Strong
pH
Not determined
Vapour Pressure
29hPa at 20°C
Density
1 g/cm³ at 20°C
Boiling Point
75°C
Melting Point
Undetermined
Solubility
Fully miscible
Specific Gravity of Density
Not determined
Flash Point
-1°C
Flammable (Explosive) Limits
Lower: 1.2 Vol %
Upper: 7 Vol %
Upper: 7 Vol %
Ignition Temperature
425 °C
Formula
Not available
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
Not available
Eye contact
No irritating effect.
Skin contact
Irritant to skin and mucous membranes.
Ingestion
Not available
Inhalation
No sensitising effects known.
Toxicity and irritation
The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version:
Toxic
Irritant.
Toxic
Irritant.
12. ECOLOGICAL INFORMATION
Ecotoxicity
No further relevant information available
Persistence and degradability
No further relevant information available
Bioaccumulative potential
No further relevant information available
Other adverse effects
Water hazard class 1: slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations. Recommended cleansing agent: Water, if necessary together with cleansing agents.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
No further relevant information available.
UN Number
UN1993
Proper shipping name
1993 Flammable liquid, N.O.S. (Toluene, Ethyl Acetate)
Transport hazard class
3 Flammable liquids
Packing group
II
Environmental hazard
Yes (DOT)
Symbol (fish and tree)
Symbol (fish and tree)
Special precautions for users
Warning: Flammable liquids.
Hazard identification number (Kemler code): 336
EMS Number: F-E,S-E
Stowage category B
Hazard identification number (Kemler code): 336
EMS Number: F-E,S-E
Stowage category B
Additional information
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category 2
Tunnel restriction code D/E
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category 2
Tunnel restriction code D/E
15. REGULATORY INFORMATION
Poisons Schedule Number
Silver S2
Toluene S6
1,7,7-Trimethylbicyclo[2.2.1]heptane-2-one S5, S6
Toluene S6
1,7,7-Trimethylbicyclo[2.2.1]heptane-2-one S5, S6
Other Information
GHS02, GHS06, GHS07, GHS08
Signal word: Danger
Hazard-determining components of labelling:
Toluene
1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
Ethyl alcohol
Ethyl acetate
Hazard statements:
highly flammable liquid and vapour
Toxic if swallowed.
Causes skin irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Signal word: Danger
Hazard-determining components of labelling:
Toluene
1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
Ethyl alcohol
Ethyl acetate
Hazard statements:
highly flammable liquid and vapour
Toxic if swallowed.
Causes skin irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
16. OTHER INFORMATION
SDS preparation date
6 December 2022
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.