SAFETY DATA SHEET
Colloidal Silver 187
1. IDENTIFICATION
Product Identifiers
Product Name:
Colloidal Silver 187
Other Names:
N/A
Product Number(s):
12684-15
CAS Number:
-
Recommended use of the chemical and restriction on use
Laboratory chemicals
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapour
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
STOT RE 2 H373 May cause damage to the hearing organs through prolonged or repeated exposure
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H336 May cause drowsiness or dizziness.
Flam. Liq. 3 H226 Flammable liquid and vapour
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
STOT RE 2 H373 May cause damage to the hearing organs through prolonged or repeated exposure
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H336 May cause drowsiness or dizziness.
Label Elements
Signal Words
Warning
Hazard Statement(s)
Flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause drowsiness or dizziness.
May cause damage to the hearing organs through prolonged or repeated exposure
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause drowsiness or dizziness.
May cause damage to the hearing organs through prolonged or repeated exposure
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Call a poison center/doctor if you feel unwell.
Specific treatment (see on this label).
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
In case of fire: Use for extinction: CO₂, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Call a poison center/doctor if you feel unwell.
Specific treatment (see on this label).
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
In case of fire: Use for extinction: CO₂, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations
Primary route(s) of entry
Human Health
Inhalation:
Not available.
Ingestion:
Not available.
Eyes:
Not available.
Skin:
Not available.
Environment
· HMIS-ratings (scale 0 - 4)
Health = 2
Fire = 4
Reactivity = 0
Health = 2
Fire = 4
Reactivity = 0
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Acetone, Reagent Grade
67-64-1
>10-≤25%
Flam. Liq. 2, H225; Eye irrt 2A, H319; STOT SE 3, H336
4-chloro-alpha,alpha,alpha-trifluorotoluene
98-56-6
>10-≤25%
Flam. Liq. 2, H226; Skin Irrit. 2, H317; Tox Aqua, H411
ethylbenzene
100-41-4
2.5-10%
Flam. Liq. 2, H225; Aspir hazard, 1 H304; Acute tox 4, H332; STOT SE2, H373
4. FIRST AID MEASURES
Ingestion
If symptoms persist consult doctor
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation
In case of unconsciousness place patient stably in side position for transportation
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, sand, extinguishing powder. Do not use water
HAZCHEM
Not available.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Do not allow to enter sewers/ surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
PAC-1:
7440-22-4 silver 0.3 mg/m³
67-64-1 Acetone, Reagent Grade 200 ppm
100-41-4 ethylbenzene 33 ppm
· PAC-2:
7440-22-4 silver 170 mg/m³
67-64-1 Acetone, Reagent Grade 3200* ppm
100-41-4 ethylbenzene 1100* ppm
· PAC-3:
7440-22-4 silver 990 mg/m³
67-64-1 Acetone, Reagent Grade 5700* ppm
100-41-4 ethylbenzene 1800* ppm
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
PAC-1:
7440-22-4 silver 0.3 mg/m³
67-64-1 Acetone, Reagent Grade 200 ppm
100-41-4 ethylbenzene 33 ppm
· PAC-2:
7440-22-4 silver 170 mg/m³
67-64-1 Acetone, Reagent Grade 3200* ppm
100-41-4 ethylbenzene 1100* ppm
· PAC-3:
7440-22-4 silver 990 mg/m³
67-64-1 Acetone, Reagent Grade 5700* ppm
100-41-4 ethylbenzene 1800* ppm
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Conditions for safe storage
Protect from heat.
Protect against electrostatic charges.
Keep respiratory protective device available.
Requirements to be met by storerooms and receptacles: Store in a cool location.
Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
67-64-1 Acetone, Reagent Grade
1000 ppm
2400 mg/m³
500 ppm
1187 mg/m³
100-41-4 ethylbenzene
100 ppm
435 mg/m³
100 ppm
435 mg/m³
67-64-1 Acetone, Reagent Grade
BEI 50 mg/L
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles
Skin protection
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Body protection
Not available.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Liquid
Odour
Characteristic
pH
Not determined
Vapour Pressure
Not determined
Density
at 20 °C (68 °F): 1.618 g/cm³ (13.50221 lbs/gal)
Boiling Point
56 °C (132.8 °F)
Melting Point
Undetermined
Solubility
Not miscible or difficult to mix
Specific Gravity of Density
Not available
Flash Point
-16 °C (3.2 °F)
Flammable (Explosive) Limits
Not flammable. Product is not explosive. However, formation of explosive air/vapour mixtures are possible.
Ignition Temperature
Product is not selfigniting
Formula
Viscosity:
Dynamic at 20 °C (68 °F): 25 mPas
· Solvent content:
Organic solvents: 22.8 %
VOC content: 1.09 %
31.7 g/l / 0.26 lb/gal
Solids content: 0.0 %
Dynamic at 20 °C (68 °F): 25 mPas
· Solvent content:
Organic solvents: 22.8 %
VOC content: 1.09 %
31.7 g/l / 0.26 lb/gal
Solids content: 0.0 %
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available
Chemical stability
Stable under normal conditions
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available
Incompatible materials
No decomposition if used according to specifications. No dangerous decomposition products known.
11. TOXICOLOGICAL INFORMATION
Acute effects
IARC (International Agency for Research on Cancer)
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene 2B
100-41-4 ethylbenzene 2B
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene 2B
100-41-4 ethylbenzene 2B
Eye contact
Causes serious eye irritation.
Skin contact
Irritant to skin and mucous membranes
Ingestion
No further relevant information available
Inhalation
No further relevant information available
Toxicity and irritation
Reproductive toxicity
Suspected of damaging the unborn child.
STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
May be fatal if swallowed and enters airways.
Suspected of damaging the unborn child.
STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
May be fatal if swallowed and enters airways.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxic for fish
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
Not available.
UN Number
UN1263
Proper shipping name
1263 PAINT, ENVIRONMENTALLY HAZARDOUS
Transport hazard class
3 Flammable liquids.
Packing group
PG II
Environmental hazard
Marine pollutant, Symbol (fish and tree)
Special precautions for users
Warning: Flammable liquids.
Additional information
Hazard identification number (Kemler code): 33
· EMS Number: F-E,S-E
· Segregation groups Liquid halogenated hydrocarbons
· Stowage Category B
ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 500 mL
· EMS Number: F-E,S-E
· Segregation groups Liquid halogenated hydrocarbons
· Stowage Category B
ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 500 mL
15. REGULATORY INFORMATION
Poisons Schedule Number
Not listed.
Section 313 (Specific toxic chemical listings):
7440-22-4 silver
100-41-4 ethylbenzene
TSCA (Toxic Substances Control Act):
7440-22-4 silver ACTIVE
67-64-1 Acetone, Reagent Grade ACTIVE
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene ACTIVE
100-41-4 ethylbenzene ACTIVE
Chemicals known to cause cancer:
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene
100-41-4 ethylbenzene
Carcinogenic categories
· EPA (Environmental Protection Agency)
7440-22-4 silver D
67-64-1 Acetone, Reagent Grade I
100-41-4 ethylbenzene D
· TLV (Threshold Limit Value established by ACGIH)
67-64-1 Acetone, Reagent Grade A4
100-41-4 ethylbenzene A3
Section 313 (Specific toxic chemical listings):
7440-22-4 silver
100-41-4 ethylbenzene
TSCA (Toxic Substances Control Act):
7440-22-4 silver ACTIVE
67-64-1 Acetone, Reagent Grade ACTIVE
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene ACTIVE
100-41-4 ethylbenzene ACTIVE
Chemicals known to cause cancer:
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene
100-41-4 ethylbenzene
Carcinogenic categories
· EPA (Environmental Protection Agency)
7440-22-4 silver D
67-64-1 Acetone, Reagent Grade I
100-41-4 ethylbenzene D
· TLV (Threshold Limit Value established by ACGIH)
67-64-1 Acetone, Reagent Grade A4
100-41-4 ethylbenzene A3
Other Information
No further relevant information available.
16. OTHER INFORMATION
SDS preparation date
17 May 2022
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.